Transition metal complexes with strong and long-lived excited state absorption: from molecular design to optical power limiting behavior

Author:

Su Huan1,Hu Lai1,Zhu Senqiang1,Lu Jiapeng1,Hu Jinyang1,Liu Rui1ORCID,Zhu Hongjun1

Affiliation:

1. School of Chemistry and Molecular Engineering, Nanjing Tech University , Nanjing , China

Abstract

Abstract Transition metal complexes (TMCs) with strong and long-lived excited state absorption (ESA) usually exhibit high-performance optical power limiting (OPL) response. Several techniques, such as transmission vs. incident fluence curves and Z-scan have been widely used to assess the OPL performance of typical TMCs. The OPL performance of TMCs is highly molecular structure-dependent. Special emphasis is placed on the structure-OPL response relationships of Pt(II), Ir(III), Ru(II), and other metal complexes. This review concludes with perspectives on the current status of OPL field, as well as opportunities that lie just beyond its frontier.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Jiangsu Province

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry

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