Platinum organometallic compounds: classification and analysis of crystallographic and structural data. Part I. Monomeric Pt(0) and partly of Pt(II) with PtC4, PtA3B and PtC2A2 chromophores-Reference-Cited by-同舟云学术

Platinum organometallic compounds: classification and analysis of crystallographic and structural data. Part I. Monomeric Pt(0) and partly of Pt(II) with PtC4, PtA3B and PtC2A2 chromophores

Published:2012-06-01 Issue:1 Volume:32 Page:23-79
ISSN:2191-0227
Container-title:Reviews in Inorganic Chemistry
language:
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Author:

Melnik Milan¹,Holloway Clive E.²

Affiliation:

1. 1Department of Inorganic Chemistry, Slovak Technical University, Radlinskeho 9, 812 37 Bratislava, Slovak Republic

2. 2Department of Chemistry, York University, 4700 Keele Street, North York, Ontario, Canada M3J 1P3

Abstract

AbstractThis review covers over 110 monomeric Pt(0) organometallics and 220 monomeric Pt(II) organometallics. The predominant geometry for Pt(0) is square planar, with some examples of two-, five-, and six-coordinated. The monomeric Pt(II) organometallics in the review covers only those with the chromophores PtC4, PtA3B and PtC2A2. The most common ligand, besides C donor ligands, which are of a wide variety, is PPh3. At least two types of isomerism occur in the platinum organometallics analysed in this review: cis-trans and distortion. Relations between Pt-ligand bond distances, bond angles and transeffect are discussed regarding steric and electronic influence.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/revic-2011-0008/pdf

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