Variable heterotridentate ligands in Pt(ƞ3-X1C1X2)(PL) (X1,2 = N or S), Pt(ƞ3-X1N1Y1)(PL) (X, Y = O, C; C, S; or O, S) and Pt(ƞ3-S1B1S2)(PL), derivatives – structural aspects-Reference-Cited by-同舟云学术

Variable heterotridentate ligands in Pt(ƞ³-X¹C¹X²)(PL) (X^1,2 = N or S), Pt(ƞ³-X¹N¹Y¹)(PL) (X, Y = O, C; C, S; or O, S) and Pt(ƞ³-S¹B¹S²)(PL), derivatives – structural aspects

Published:2024-01-19 Issue:3 Volume:44 Page:339-345
ISSN:0193-4929
Container-title:Reviews in Inorganic Chemistry
language:en
Short-container-title:

Author:

Melník Milan¹,Žigrayová Dominika²,Mikušová Veronika²,Mikuš Peter¹³

Affiliation:

1. Faculty of Pharmacy, Department of Pharmaceutical Analysis and Nuclear Pharmacy , Comenius University in Bratislava , Odbojárov 10 , Bratislava , SK-832 32 Slovak Republic

2. Faculty of Pharmacy, Department of Galenic Pharmacy , Comenius University in Bratislava , Odbojárov 10 , Bratislava , SK-832 32 Slovak Republic

3. Faculty of Pharmacy, Toxicological and Antidoping Centre , Comenius University in Bratislava , Odbojárov 10 , Bratislava , SK-832 32 Slovak Republic

Abstract

Abstract This review covers 17 Pt(II) complexes of the compositions: Pt(ƞ3-N1C1N2)(PL), Pt(ƞ3-S1C1S2)(PL), Pt(ƞ3-S1B1S2)(PL), Pt(ƞ3-S1S2O1)(PL), Pt(ƞ3-O1N1C1)(PL), Pt(ƞ3-O1N1S1)(PL) and Pt(ƞ3-C1N1S1)(PL). These complexes crystallized in three crystal classes: monoclinic (8 examples), triclinic (8 examples) and orthorhombic (1 example). The heterotridentate ligands creates 5 + 5-membered metallocyclic rings (most common) and 5 + 6-membered. The heterotridentate ligands with monodentate P ligands build up a distorted square-planar geometry about Pt(II) atoms. The Pt–L and L–Pt–L were analyzed. The τ 4 parameter which indicate a degree of distortion growing in the sentence: 0.057 Pt(ƞ3-O1N1S1)(PL) < 0.066 Pt(ƞ3-S1C1S2)(PL) < 0.149 Pt(ƞ3-S1S2O1)(PL) < 0.158 Pt(ƞ3-O1N1C1)(PL) < 0.160 Pt(ƞ3-C1N1S1)(PL) < 0.162 Pt(ƞ3-S1B1S2)(PL) < 0.165 Pt(ƞ3-N1C1N2)(PL).

Funder

The Faculty of Pharmacy, Comenius University Bratislava

Publisher

Walter de Gruyter GmbH

Link

https://www.degruyter.com/document/doi/10.1515/revic-2023-0029/pdf

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