A review on the chemistry of novel platinum chelates based on azo-azomethine ligands

Author:

Mandal Paritosh1,Pratihar Jahar L.2

Affiliation:

1. Department of Chemistry , Fatepuria College , Beldanga 742133 , W.B. , India

2. Department of Chemistry , Krishnath College , Berhampore 742101 , India

Abstract

Abstract Numerous platinum group metals (PGMs) complexes contain azo-azomethine-based ligands. Azo-azomethine ligands are N-donor ligands that have extended conjugated π-bonded systems and both azo (–N=N–) and aldimine (–C=N–) functions in their structure. Plenty of platinum (Pt) complexes with azo-imine ligands have been prepared and characterized. Various multidentate azo-imine ligands coordinated with different platinum metal substrates afforded structurally diverse platinum chelates. Nonetheless, many azo-imine-based platinum complexes demonstrated a wide range of biological activities, photo-switchable properties, and redox activities. The review encompasses a general overview of platinum complexes with versatile azo-azomethine ligands, their synthetic protocol, spectroscopic and structural features, chemical reactivity, and multipurpose applications in different areas.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry

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