Dehydrogenative borylation: the dark horse in metal-catalyzed hydroborations and diborations?-Reference-Cited by-同舟云学术

Dehydrogenative borylation: the dark horse in metal-catalyzed hydroborations and diborations?

Published:2015-06-01 Issue:2 Volume:35 Page:69-79
ISSN:2191-0227
Container-title:Reviews in Inorganic Chemistry
language:
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Author:

Geier Stephen J.¹,Westcott Stephen A.¹

Affiliation:

1. 1Department of Chemistry and Biochemistry, Mount Allison University, Sackville, New Brunswick, Canada E4L 1G8

Abstract

AbstractMetal-catalyzed hydroborations and diborations frequently give “unwanted” side products arising from a competing dehydrogenative borylation reaction. While catalyst development initially focused on avoiding this “deleterious” pathway, fine tuning of a catalyst system could provide an efficient method to generate unsaturated alkenylboronate esters, synthetically valuable synthons for the Suzuki-Miyaura cross-coupling reaction. The aim of this review is to highlight the history and development of the dehydrogenative borylation reaction in the metal-catalyzed synthesis of alkenylboronate esters.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/revic-2014-0008/pdf

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