Author:
Hájek Bohumil,Muck Alexander,Smrčková Olga
Abstract
The infrared spectra were studied for the pyramidal ClO3- anion (C3v) embedded in host structures of various symmetries. Small amounts of NaClO3 or KClO3 were incorporated in NaBrO3 (T4), NaIO3 (D162h), KBrO3 (C3v5), and KIO3 (C11) structures. The ClO3- anion was found to assume the site symmetry of the host structure anion, i.e. C3, Cs, C3v, and C1, respectively, in accordance with the results of group analysis.
Publisher
Institute of Organic Chemistry & Biochemistry
Cited by
2 articles.
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