Role of Water in Synthesis of Higher Alcohols from CO and H2 over MoS2
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Published:1997
Issue:1
Volume:62
Page:130-135
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ISSN:0010-0765
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Container-title:Collection of Czechoslovak Chemical Communications
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language:en
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Short-container-title:Collect. Czech. Chem. Commun.
Author:
Andreev Atanas A.,Mintchev Lubomir S.,Gabrovska Margarita V.
Abstract
Experimental evidence was found in support of the direct participation of water in synthesis reactions from CO and hydrogen over MoS2 and K/MoS2 through its dissociation to activated OH and H. A reaction mechanism based on a common formate intermediate in alcohol and hydrocarbon synthesis and water-gas shift reaction is proposed.
Publisher
Institute of Organic Chemistry & Biochemistry
Subject
General Chemistry