Synthesis and Characterization of Heterodinuclear Complexes Pentacarbonyl[(dimethylaminomethyl)ferrocene]molybdenum and Pentacarbonyl[(dimethylaminomethyl)ferrocene]tungsten-Reference-Cited by-同舟云学术

Synthesis and Characterization of Heterodinuclear Complexes Pentacarbonyl[(dimethylaminomethyl)ferrocene]molybdenum and Pentacarbonyl[(dimethylaminomethyl)ferrocene]tungsten

Published:2000 Issue:1 Volume:65 Page:23-34
ISSN:0010-0765
Container-title:Collection of Czechoslovak Chemical Communications
language:en
Short-container-title:Collect. Czech. Chem. Commun.

Author:

Pavlík Ivan,Pavlišta Martin,Jacob Klaus,Pietzsch Claus,Lébl Tomáš,Vinklárek Jaromír

Abstract

(Dimethylaminomethyl)ferrocene (HFcR, R = CH2NMe2) reacts with Mo(CO)6 and W(CO)6 under substitution of one CO group and formation of the donor-acceptor complexes of the formula HFcR·M(CO)5 (M = Mo, W). These yellow microcrystalline derivatives were characterized by mass, UV-VIS, IR, NMR and Mössbauer spectroscopy.

Publisher

Institute of Organic Chemistry & Biochemistry

Subject

General Chemistry

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