Preparation of 1-Adamantyl Ketones: Structure, Mechanism of Formation and Biological Activity of Potential By-Products-Reference-Cited by-同舟云学术

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Preparation of 1-Adamantyl Ketones: Structure, Mechanism of Formation and Biological Activity of Potential By-Products

Published:2006 Issue:5 Volume:71 Page:709-722
ISSN:0010-0765
Container-title:Collection of Czechoslovak Chemical Communications
language:en
Short-container-title:Collect. Czech. Chem. Commun.

Author:

Vícha Robert,Nečas Marek,Potáček Milan

Abstract

Reactions between adamantane-1-carbonyl chloride and several Grignard reagents as well as interactions with solvents have been examined. Some new and unexpected adamantane derivatives were isolated, fully characterized and their biological activity determined. In particular, an unexpected isochromanone 16 was formed in an SEAr process, in which a stable hydrocarbon was the leaving group.

Publisher

Institute of Organic Chemistry & Biochemistry

Subject

General Chemistry

Cited by 9 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Synthesis, molecular structure and vibrational spectra of 1,3-bis(1-adamantyl)-2-phenylpropan-1,3-diones;Journal of Molecular Structure;2015-04

2. Conformational dimorphism of isochroman-1-ones in the solid state;Journal of Molecular Structure;2014-12

3. 2-(Adamantan-1-yl)-1,3-bis(4-methylphenyl)propan-2-ol;Acta Crystallographica Section E Structure Reports Online;2012-12-19

4. Rhenium complex-catalyzed acylative cleavage of ethers with acyl chlorides;Tetrahedron;2011-09

5. (1-Adamantyl)(2-methylphenyl)methanone;Acta Crystallographica Section E Structure Reports Online;2010-11-24

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