Author:
Vičar Jaroslav,Piriou François,Fromageot Pierre,Bláha Karel,Fermandjian Serge
Abstract
The diastereoisomeric pairs of cyclodipeptides cis- and trans-cyclo(Ala-Ala), cyclo(Ala-Phe), cyclo(Val-Val) and cyclo(Leu-Leu) containing 85% 13C enriched amino-acid residues were synthesized and their 13C-13C coupling constants were measured. The combination of 13C-13C and 1H-1H coupling constants enabled to estimate unequivocally the side chain conformation of the valine and leucine residues.
Publisher
Institute of Organic Chemistry & Biochemistry
Cited by
11 articles.
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