Author:
Bystrický Slavomír,Sticzay Tibor,Tvaroška Igor
Abstract
Conformational mobility of tetruloses, 2-pentuloses, D-3-pentulose and 4-deoxy-L-pentulose was studied by measuring temperature dependences of CD spectra in the region +40°C to -140°C in a methanol-ethanol (1:4) mixture. The changes in spectra reflect the population of rotamers around bonds to the carbonyl chromophore. The most stable conformers were determined by PCILO quantum chemical calculation.
Publisher
Institute of Organic Chemistry & Biochemistry
Cited by
2 articles.
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