The oxygen basicity strengthening effect in peroxides
-
Published:1980
Issue:3
Volume:45
Page:876-879
-
ISSN:0010-0765
-
Container-title:Collection of Czechoslovak Chemical Communications
-
language:en
-
Short-container-title:Collect. Czech. Chem. Commun.
Author:
Pola Josef,Chvalovský Václav
Abstract
The hydrogen-bonding ability of peroxides R3MOOM'R'3 having M = C, Si and Ge with phenol in CCl4 is analyzed. The oxygen basicity of the R3MOOM'R'3 with M = C and Si is indicated to be increased over the ability of the electronic effect of R3C- and R3Si- groups probably due to the interaction between lone electron pairs located at the oxygen atoms.
Publisher
Institute of Organic Chemistry & Biochemistry
Subject
General Chemistry