Conditions of formation of alkali hydrogenphosphites-Reference-Cited by-同舟云学术

Conditions of formation of alkali hydrogenphosphites

Published:1980 Issue:11 Volume:45 Page:3069-3080
ISSN:0010-0765
Container-title:Collection of Czechoslovak Chemical Communications
language:en
Short-container-title:Collect. Czech. Chem. Commun.

Author:

Lukeš Ivan,Ebert Miroslav

Abstract

The Filippov's eutonic method was applied to the study of M2HPO3-H3PO3-H2O heterogeneous systems (M = Li, Na, K) at 25 °C. The values of the standard Gibbs energy changes for the reactions occurring in these systems were obtained. The highest changes in the Gibbs energy accompany the formation of hydrogenphosphites M(H2PO3), the energy increases from Li to K and decreases from hydrogenphosphite to tris(orthophosphite) and bis(orthophosphite).

Publisher

Institute of Organic Chemistry & Biochemistry

Subject

General Chemistry

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