Radical Addition of Triethylamine and 1-Methylpiperidine to Tetrafluoroethene
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Published:1994
Issue:11
Volume:59
Page:2501-2510
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ISSN:0010-0765
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Container-title:Collection of Czechoslovak Chemical Communications
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language:en
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Short-container-title:Collect. Czech. Chem. Commun.
Author:
Hampl František,Liška František
Abstract
The radical addition of triethylamine (I) and 1-methylpiperidine (II) to tetrafluoroethene (III) initiated by UV and γ-60Co radiation produces tertiary amines containing 1,1,2,2-tetrafluoroethyl group at α-position (1 : 1 adducts) and/or at α,α'-positions (1 : 2 adducts). 1 : 2 Telomers, 1 : 3 adducts, and products formed by recombination of 1 : 1 adduct radicals represent minor products.
Publisher
Institute of Organic Chemistry & Biochemistry
Subject
General Chemistry