Binuclear complexes of aminoacetohydroxamic acid with copper(II) and iron(III)-Reference-Cited by-同舟云学术

Binuclear complexes of aminoacetohydroxamic acid with copper(II) and iron(III)

Published:1987 Issue:3 Volume:52 Page:592-601
ISSN:0010-0765
Container-title:Collection of Czechoslovak Chemical Communications
language:en
Short-container-title:Collect. Czech. Chem. Commun.

Author:

Karlíček Rolf,Polášek Miroslav

Abstract

Aminoacetohydroxamic acid (glycinehydroxamic acid, H2NCH2CONHOH) (HL) forms the complex species FeHL3+, Cu2H-1L2+ and CuFeH-1L3+ at cM > cL. The two binuclear complexes were proved to be formed with the elimination of two hydrogen ions from one hydroxamic functional group, the amide nitrogen atom of the hydroxamic group taking part in the coordination. The spectrophotometric characteristics of the complexes and the equilibrium constants of the reactions involved are given.

Publisher

Institute of Organic Chemistry & Biochemistry

Subject

General Chemistry

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