The infrared spectra of tetrahedral anions in mixed crystals-Reference-Cited by-同舟云学术

The infrared spectra of tetrahedral anions in mixed crystals

Published:1984 Issue:8 Volume:49 Page:1756-1763
ISSN:0010-0765
Container-title:Collection of Czechoslovak Chemical Communications
language:en
Short-container-title:Collect. Czech. Chem. Commun.

Author:

Hájek Bohumil,Smrčková Olga,Záruba Petr

Abstract

Group Analysis of the infrared spectra of KClO4-KMnO4, KClO4-KBF4 and K2SO4-K2XO4 (where X is Se, Cr, Mn) mixed crystals was carried out. These systems form D2h16 orthorhombic substitution mixed crystals; the symmetry of the anion is Td. Analysis of the infrared spectra samples with sufficiently diluted studied anion revealed the expected decrease in symmetry to Cs symmetry.

Publisher

Institute of Organic Chemistry & Biochemistry

Subject

General Chemistry

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