Effect of Triton X100 on Tetramethylammonium Ion Transport Kinetics Through the Water/Nitrobenzene Interface
-
Published:1995
Issue:9
Volume:60
Page:1435-1447
-
ISSN:0010-0765
-
Container-title:Collection of Czechoslovak Chemical Communications
-
language:en
-
Short-container-title:Collect. Czech. Chem. Commun.
Author:
Wawrzynczak Wojciech S.,Figaszewski Zbigniew
Abstract
The tetramethylammonium cation (TMA+) transport through the water/nitrobenzene interface modified by the Triton X100 (TX100) adsorption has been investigated using cyclic voltammetry and interfacial tension measurements. Obtained results indicate the strong adsorption of TX100 and its responsible effect on the TMA+ ion transfer. Adsorption data have been fitted to six theoretical adsorption isotherm equations with the best fitting for the Frumkin isotherm. The mechanism of facilitating effect of TX100 on the TMA+ transfer has been proposed. The suggested mechanism is different from that developed by other authors.
Publisher
Institute of Organic Chemistry & Biochemistry
Subject
General Chemistry
Cited by
1 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献