Author:
Kellö Eleonóra,Lokaj Jan,Vrábel Viktor
Abstract
The structure of [Co{S2CN(CH2-CH=CH2)2}3] was determined by the heavy atom method, all nonhydrogen atoms being refined by anisotropic diagonal approximation using the least squares method to the value of R= 0.067 for 1 024 reflections with I ≥ 1.96σ(I). The substance is isostructural with [Fe{S2CN(CH2-CH=CH2)2}3], crystallizes in the monoclinic system, space group C2/c, lattice parameters a = 1.8763(9), b = 1.0209(5), c = 1.5402(7) nm, β = 106.18(4)°, Z = 4. Cobalt is coordinated by 3 dithiocarbamate ligands in the bidentate way, the average Co-S lenght is 0.2267(2) nm. The metal atom and two ligand atoms are located on the twofold axis. The CoS6 polyhedron is a trigonally distorted octahedron.
Publisher
Institute of Organic Chemistry & Biochemistry
Cited by
8 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Ni(II), Pd(II) and Pt(II) complexes of N,N-bis(3,3-dimethyl-allyl)-dithiocarbamate: Synthesis, spectroscopic characterization, antimicrobial and molecular docking studies;Journal of Molecular Structure;2022-02
2. Synthesis, characterization, and electrochemical studies of Co(II, III) dithiocarbamate complexes;Journal of Coordination Chemistry;2019-04-03
3. Organomercury complexes bearing (thioxothiazolidin-5-yl)methyl moiety by intramolecular heteromercuration reaction of diallyldithiocarbamate;Inorganica Chimica Acta;2018-02
4. Tris dithiocarbamate of Co(III) complexes: Synthesis, characterization, thermal decomposition studies and experimental and theoretical studies on their crystal structures;Journal of Molecular Structure;2017-04
5. Ring-Closing Metathesis and Nanoparticle Formation Based on Diallyldithiocarbamate Complexes of Gold(I): Synthetic, Structural, and Computational Studies;Inorganic Chemistry;2014-02-10