1,2-Bis(azacrown)ethanes: Effect of Bridge Substitution and Ring Size on Formation of Sandwich Complexes with Sodium and Potassium Ions-Reference-Cited by-同舟云学术

1,2-Bis(azacrown)ethanes: Effect of Bridge Substitution and Ring Size on Formation of Sandwich Complexes with Sodium and Potassium Ions

Published:1993 Issue:1 Volume:58 Page:153-158
ISSN:0010-0765
Container-title:Collection of Czechoslovak Chemical Communications
language:en
Short-container-title:Collect. Czech. Chem. Commun.

Author:

Bělohradský Martin,Holý Petr,Koudelka Juraj,Závada Jiří

Abstract

The title problem was investigated potentiometrically using four homologous series of bis(azacrown)s I-IV. A surprisingly large destabilizing effect of bridge substituent was found in the intramolecular sandwich complex formation and ascribed to symmetry violation.

Publisher

Institute of Organic Chemistry & Biochemistry

Subject

General Chemistry

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