A Theoretical Study of Neighboring-Group Participation in Thione-to-Thiol Rearrangement of Xanthates. Molecular Orbital Calculation Using a Conductor-Like Screening Model (COSMO) Approach.
Author:
Affiliation:
1. Faculty of Pharmaceutical Sciences, Kumamoto University
Publisher
Pharmaceutical Society of Japan
Subject
Drug Discovery,General Chemistry,General Medicine
Link
http://www.jstage.jst.go.jp/article/cpb/49/11/49_11_1433/_pdf
Reference28 articles.
1. Transition Structures of Hydrocarbon Pericyclic Reactions
2. Sequential pericyclic reaction of unsaturated xanthates. Intramolecular cycloaddition selectivity of the 2,4-alkadienyl 2-alkenyl sulfides
3. Retro-ene type fragmentation of allylic dithiolcarbonates
4. Rearrangement and trans-elimination contrary to the chugaev reaction rule. XIII. Solvent effect on rearrangement reaction of allylic xanthates and a correction of the former report.
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