SYNTHESIS AND STUDY OF STRUCTURAL PROPERTIES OF COMPOSITES BASED ON NI-RU FOR STEAM CONVERSION OF ETHANOL-Reference-Cited by-同舟云学术

SYNTHESIS AND STUDY OF STRUCTURAL PROPERTIES OF COMPOSITES BASED ON NI-RU FOR STEAM CONVERSION OF ETHANOL

Published:2020-04-15 Issue:440 Volume:2 Page:138-144
ISSN:2518-1491
Container-title:SERIES CHEMISTRY AND TECHNOLOGY
language:en
Short-container-title:

Author:

Naurzkulova S.M.¹^ORCID,Massalimova B.K.²^ORCID,Shorayeva K.A.³,Dzhienbaeva G.М.⁴,Arapova M.V.⁵,Sadykov V.A.⁶^ORCID

Affiliation:

1. 2-year PhD student of specialty chemistry, M.Kh. DulatiTaraz State University, Tole bi str. 60, Taraz, Kazakhstan, simbat_3@mail.ru, https://orcid.org/0000-0002-2144-233X

2. candidate of chemical sciences, associated professor, manager of the department of “Chemistry and chemical technology”, M.Kh. DulatiTaraz State University, Tole bi str. 60, Taraz, Kazakhstan, massalimova15@mail.ru, https://orcid.org/0000-0003-0135-9712

3. 3-year PhD student of specialty chemistry, M.Kh. DulatiTaraz State University, Tole bi str. 60, Taraz, Kazakhstan, k.a.shorayeva@mail.ru;

4. 2-year master’s student of specialty chemistry, M.Kh. DulatiTaraz State University, Tole bi str. 60, Taraz, Kazakhstan,Dzhienbaeva.G.@mail.ru;

5. candidate of chemical sciences,Boreskov Institute of Catalysis, Novosibirsk, Russia, arapova@catalysis.ru;

6. doctor of chemical sciences, professor, Boreskov Institute of Catalysis, Novosibirsk, Russia, vasadykov@mail.ru, sadykov@catalysis.ru, https://orcid.org/0000-0003-2404-0325

Abstract

Сatalyst precursors, substituted by rare-earth and transition metals, promoted with Ru nanoparticles using the modified Pechinimethod (Organic polymeric precursor) have been synthesized. To transform biofuel (ethanol) into hydrogen from the obtained active phases, three different methods were used to synthesize composites with the general formula [LaMn1-xBxO3 + δ / Ln1-yZryO2] (1: 1 by mass), B = Ni, Ru, Ln = Pr, Sm , Ce. Structural and surface properties of the obtained samples of complex oxides and composites were studied using the BET and XPA methods. The textural and structural characteristics of composites differing in the methods of their preparationare presented. Key words: perovskite, fluorite, composites, biomass, hydrogen.

Publisher

National Academy of Sciences of the Republic of Kazakshtan

Link

http://chemistry-technology.kz/images/pdf/h20202/138-144.pdf

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