THE CRYSTAL AND MOLECULAR STRUCTURE OF BENZYL (2-METHOXYPHENYL)-DIPHENYLPHOSPHONIUM BROMIDE-Reference-Cited by-同舟云学术

THE CRYSTAL AND MOLECULAR STRUCTURE OF BENZYL (2-METHOXYPHENYL)-DIPHENYLPHOSPHONIUM BROMIDE

Published:1977-04 Issue:2 Volume:3 Page:163-169
ISSN:0308-664X
Container-title:Phosphorus and Sulfur and the Related Elements
language:en
Short-container-title:Phosphorus and Sulfur and the Related Elements

Author:

Wood John S.¹,Wikholm Ronald J.¹,McEwen William E.¹

Affiliation:

1. a Department of Chemistry , University of Massachusetts , Amherst , MA. , 01002

Publisher

Informa UK Limited

Subject

General Medicine

Link

https://www.tandfonline.com/doi/pdf/10.1080/03086647708077706

Reference22 articles.

1. Additional evidence of a new type of anchimeric assistance in quaternization reactions of phosphines and arsines

2. Chemical and physical consequences of 2p-3d overlap in o-anisylphosphines and o-anisylphosphonium salts

3. Schulz has suggested that the rate acceleration might be the result of a polarization of the lone pair of electrons on phosphorus caused by a repulsion interaction with a pair of 2pelectrons on the methoxy group.5Of course, at some point during the course of the reaction, this type of interaction would become a partially bonding one as the phosphorus becomes positively charged. However, such a changeover in the nature of the interaction would not necessarily coincide with the transition state of the reaction. McEwen et al.2also pointed out that the influence of theo-methoxy group may be partly or completely the result of a field effect rather than an overlap effect

4. Ph. D. Dissertation;Schulz D. N.,1971

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4. Crystal Structure and Chemical Properties of Tris(2,6-dimethoxyphenyl)phosphine Selenide;Bulletin of the Chemical Society of Japan;1996-03

5. Tris(2,6-dimethoxyphenyl)phosphine sulfide monohydrate;Acta Crystallographica Section C Crystal Structure Communications;1994-08-15