Alumazene adducts with triphenylphosphine oxide
Author:
Publisher
IOS Press
Subject
Materials Chemistry,Inorganic Chemistry,Organic Chemistry
Reference28 articles.
1. The molecular and solid‐state structure of borazine has been determined at 115 and 160 K by single‐crystal X‐ray crystallography. The molecular structure has C 2 symmetry with small deviations from the expected D 3 h symmetry. The mean value of the BN bond length is 1.429(1) A and the interbond angles of the six‐membered ring are 117.1(1)° at the boron atoms and 122.9(1)° at the nitrogen atoms (mean values). Similar to benzene an unambiguous assignment of the molecular symmetry is not possible. — The crystal packing is not comparable to any known phase of benzene, and surprisingly the molecules are not stacked having coplanar rings. Instead, the molecules are found in tilted layers. No significant intermolecular interaction could be detected. The generated difference electron density maps show the typical distribution pattern for polar bonds.
2. Synthesis and X-Ray Structure of(2,4,6-Me3C6H2BPC6H11)3: A Boron-Phosphorus Analogue of Borazine
3. Boron-phosphorus analogs of benzene and cyclobutadiene. Synthesis and characterization of the boraphosphabenzenes (RBPR')3 (R = Mes, Ph; R' = Ph, Mes, C6H11, tert-Bu) and the diphosphadiboretane (thexylBPMes)2
4. Synthesis and Structure of [MeAlN(2,6-iPr2C6H3)]3: An Aluminum-Nitrogen Analogue of Borazine
5. Reactions of trimethylaluminum or trimethylgallium with bulky primary amines: structural characterization of the thermolysis products
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1. Trapping of a Transient Base‐Stabilised Alumylene and Alumylene‐Type Reactivity of a Self‐Stabilising Dialumene towards Organic Azides;Chemistry – A European Journal;2023-04-20
2. A Monomeric Aluminum Imide (Iminoalane) with Al–N Triple-Bonding: Bonding Analysis and Dispersion Energy Stabilization;Journal of the American Chemical Society;2021-04-21
3. Alumazene Reactivity with Quinolinols – Addition and Substitution Reactions on the Al3N3 Ring;Acta Chimica Slovenica;2018-12-15
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