Coordination behavior of organothiophosphate ligands towards trivalent lanthanide complexes and potential use as V-series chemical warfare agent simulants

Author:

Sambrook Mark R.1ORCID,Althoff Marc André2,Karaghiosoff Konstantin L.2,Metzulat Manfred3,Dennison Genevieve H.4ORCID

Affiliation:

1. CBR Division, Defence Science and Technology Laboratory (Dstl), Porton Down, Salisbury, UK;

2. Department of Chemistry, Ludwig-Maximilians, University, Munich, Germany;

3. Science Division, Chemistry Section, CBRN-Defence Safety and Environmental Protection School, Sonthofen, Germany;

4. Land Division, Defence Science and Technology Group, Fishermans Bend, Melbourne, Australia

Publisher

Informa UK Limited

Subject

Materials Chemistry,Physical and Theoretical Chemistry

Reference27 articles.

1. (a) K. Kim, O.G. Tsay, D.A. Atwood, D.G. Churchill.Chem. Rev.,111, 5345 (2011).

2. The Chemistry of Organophosphorus Chemical Warfare Agents

3. (a) U. Ivarsson, H. Nilsson, J. Santesson (Eds.),A FOA Briefing Book on Chemical Weapons: Threat, Effects, and Protection, National Defence Research Establishment, Umea (1992).

4. (b) Organisation for the Prohibition of Chemical Weapons (OPCW), https://www.opcw.org/our-work/what-chemical-weapon Convention on the prohibition of the development, production, stockpiling and use of chemical weapons and on their destruction, Annex on Chemicals, OPCW, The Hague, The Netherlands (1997).

5. Experimental and computational study of the inclusion complexes of β-cyclodextrin with the chemical warfare agent soman (GD) and commonly used simulants

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