Reactivity of (Triphos)FeBr2(CO) towards sodium borohydrides-Reference-Cited by-同舟云学术

Reactivity of (Triphos)FeBr2(CO) towards sodium borohydrides

Published:2016-06-16 Issue:11-13 Volume:69 Page:2038-2046
ISSN:0095-8972
Container-title:Journal of Coordination Chemistry
language:en
Short-container-title:Journal of Coordination Chemistry

Author:

Mukhopadhyay Tufan K.¹,Groy Thomas L.¹,Smythe Nathan C.²,Gordon John C.²,Trovitch Ryan J.¹

Affiliation:

1. School of Molecular Sciences, Arizona State University, Tempe, AZ, USA

2. Chemistry Division, Los Alamos National Laboratory, Los Alamos, NM, USA

Funder

Los Alamos National Laboratory

Publisher

Informa UK Limited

Subject

Materials Chemistry,Physical and Theoretical Chemistry

Link

https://www.tandfonline.com/doi/pdf/10.1080/00958972.2016.1191631

Reference41 articles.

1. For the purposes of this manuscript, Triphos refers to PhP(CH2CH2PPh2)2. In some articles, Triphos is used as a descriptor for the more rigid chelate, H3CC(CH2CH2PPh2)3.

2. Polytertiary phosphines and arsines. III. Metal complexes of the tritertiary phosphine bis(2-diphenylphosphinoethyl)phenylphosphine

3. Photochemical generation of a reactive transition-metal fragment. Photochemically induced arene replacement reactions of the cyclopentadienyl(p-xylene)iron(II) ion

4. Hydride reduction of the cation [(η5-C5H5)Fe(triphos)]PF6: direct nucleophilic attack on the metal, and hydrogen exchange in the product hydride (η5-C5H5)FeH(triphos)(triphos = Ph2PCH2CH2PPhCH2CH2PPh2)

5. Electron-rich cations: preparation and hydride reductions of the cations [Fe(η5-C5H5){PhP(CH2CH2PPh2)2}]+, [Fe(η5-C5H5){MeC(CH2PPh2)3}]+, and [Fe(η5-C5H5){C(CH2PPh2)4}]+

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