Triple B≡B bond: from a perfect Lewis structure to a dominant π-back-donation. The need for a reference point
Author:
Affiliation:
1. Department of Chemical Sciences, Ariel University, Ariel, Israel;
2. Department of Chemistry, Hebrew University of Jerusalem, Jerusalem, Israel
Publisher
Informa UK Limited
Subject
Materials Chemistry,Physical and Theoretical Chemistry
Link
https://www.tandfonline.com/doi/pdf/10.1080/00958972.2018.1490728
Reference34 articles.
1. A Boron-Boron Triple Bond
2. Single, Double, Triple Bonds and Chains: The Formation of Electron-Precise BB Bonds
3. OCBBCO: A Neutral Molecule with Some Boron−Boron Triple Bond Character
4. Infrared Spectra of BCO, B(CO)2, and OCBBCO in Solid Argon
5. Ambient-Temperature Isolation of a Compound with a Boron-Boron Triple Bond
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1. The Search for Enhanced σ‐Donor Ligands to Stabilize Boron‐Boron Multiple Bonds;European Journal of Inorganic Chemistry;2023-01-19
2. Cyclo-, Closo- and hypercloso-aminoboranes; B-B bonding, 3D-aromaticity, stability and NICS values;Polyhedron;2022-08
3. In Search of the Perfect Triple BB Bond: Mechanical Tuning of the Host Molecular Trap for the Triple Bond B≡B Fragment;Molecules;2021-10-25
4. Revisiting the π-Back-Donation in the NHC–B≡B–NHC Molecule;The Journal of Physical Chemistry A;2021-02-17
5. The nature of the triple B B, double, B B, single, B–B, and one-electron, B.B boron-boron bonds from the topological analysis of electron localisation function (ELF) perspective;Journal of Molecular Structure;2020-12
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