Alumina as a Desilicohalogenating Agent in the Stereoselective Synthesis of Vinyl Halides

Author:

Miller R. Bryan,McGarvey Glenn

Publisher

Informa UK Limited

Subject

Organic Chemistry

Reference5 articles.

1. The stereospecific synthesis of vinyl halides using a vinylsilane as the synthetic precursor

2. Chemistry of bent bonds. XLIII. Cycloadditions to cyclic 1,3-dienes. Diels-Alder route to inside-outside bicyclics

3. Prepared from 1-hexyne by chloroplatinic acid - catalyzed hydrosilylation with dimethylchlorosilane followed by treatment with methyl magnesium bromide.4

4. The Stereochemistry of the Addition of Silicochloroform to Acetylenes. A Comparison of Catalyst Systems

5. The δ value for compounds containing a trimethylsilyl group are reported in ppm down field from internal -Si(CH3)3, not from TMS.

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1. Halogenation of Organometallics;Comprehensive Organic Transformations;2018-02-28

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3. Process Development for a Large Scale Stereoselective Synthesis of (Z)-(1-Bromobut-1-ene-1,2-diyl)dibenzene, a Key Intermediate of a Selective Estrogen Receptor Modulator;Organic Process Research & Development;2010-09-02

4. Activating and Directive Effects of Silicon;PATAI'S Chemistry of Functional Groups;2009-12-15

5. Preparation of Difunctional Compounds;Compendium of Organic Synthetic Methods;2006-11-22

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