Synthesis, Spectroscopic Characterization and X-Ray Crystal Structure of the Chloride-Bridged Face-Sharing Bioctahedral Diiridium Complex [HP-t-Bu2Me][Ir2Cl7(P-t-Bu2Me)2], a Possible Precursor of the Complex [Ir(H)(Cl)2(P-t-Bu2Me)2]
Author:
Affiliation:
1. a Istituto di Strutturistica Chimica “G. Giacomello”, Area della Ricerca di Roma , CNR, C.P.No. 10, 00016, Monterotondo Stazione, Rome, Italy
Publisher
Informa UK Limited
Subject
Materials Chemistry,Physical and Theoretical Chemistry
Link
https://www.tandfonline.com/doi/pdf/10.1080/00958970008055131
Reference10 articles.
1. Syntheses, spectroscopic characterization and X-ray crystal structures of [HP-i-Pr3]2[IrCl6] (1), [HP-i-Pr3]2[Ir2Cl8(P-i-Pr3)] (2) and [HP-i-Pr3] [Ir2Cl7(P-i-Pr3)2] (3): three possible precursors of the complex Ir(H) (Cl)2(P-i-Pr3)2 (4)
2. SYNTHESIS AND X-RAY CRYSTAL STRUCTURE OF THE CHLORIDE-BRIDGED FACE-SHARING BIOCTAHEDRAL DIRHODIUM COMPLEX [HP-i-Pr3][Rh2Cl7(P-i-Pr3)2]
3. Do paramagnetic platinum metal hydrides really exist? A reinvestigation of the synthesis and magnetochemical properties of Ir(H)x(Cl)2(P-i-Pr3)2 (1). Syntheses and crystal structure determinations of trans-Ir(H)(Cl)2(CO)(P-i-Pr3)2 (2), cis-Ir(H)(Cl)2(CO)(P-i-Pr3)2 (4) and trans-Ir(Cl)(CO)(P-i-Pr3)2 (5)
4. Iridium complexes of tertiary t-butyl- and di-t-butylphosphines including some five-co-ordinate iridium(III) complexes with hydride resonances at τca. 60
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1. Di-tert-butyl(methyl)phosphine;Encyclopedia of Reagents for Organic Synthesis;2014-05-27
2. NMR Studies of the Reaction Path of the o-H2/p-H2 Spin Conversion Catalyzed by Vaska’s Complex in the Solid State;Applied Magnetic Resonance;2012-10-16
3. Relativistic Four-Component DFT Calculations of 1H NMR Chemical Shifts in Transition-Metal Hydride Complexes: Unusual High-Field Shifts Beyond the Buckingham–Stephens Model;The Journal of Physical Chemistry A;2011-05-17
4. Bridged diiridium complexes for electrophosphorescent OLEDs: synthesis, X-ray crystal structures, photophysics, and devices;Journal of Materials Chemistry;2006
5. Crystal Structure of Tri-.MU.-chloro-bis[(1,2,3,4,5-.ETA.)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl)]-diiridium Tetrafluoroborate with a Unique Trigonal-bipyramidal Ir2Cl3 Core, [Ir2(Cp*)2(.MU.-Cl)3]BF4 (Cp* =.ETA.5-C5Me5);Analytical Sciences: X-ray Structure Analysis Online;2004
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