Convergent synthesis of 4,5-branched inner-core oligosaccharides of lipopoly- and lipooligosaccharides-Reference-Cited by-同舟云学术

Convergent synthesis of 4,5-branched inner-core oligosaccharides of lipopoly- and lipooligosaccharides

Published:2015-12-02 Issue:12 Volume:79 Page:1931-1945
ISSN:0916-8451
Container-title:Bioscience, Biotechnology, and Biochemistry
language:en
Short-container-title:

Author:

Yi Ruiqin¹,Narimoto Hirofumi²,Nozoe Miku²,Ichiyanagi Tsuyoshi²

Affiliation:

1. The United Graduate School of Agricultural Sciences, Tottori University, Tottori, Japan

2. Faculty of Agriculture, Department of Life and Food Sciences, Tottori University, Tottori, Japan

Abstract

Abstract The convergent synthesis of branched inner-core oligosaccharides of lipopoly- and lipooligosaccharide with a 3-deoxy-d-manno-oct-2-ulosonic acid (Kdo) disaccharide acceptor was achieved. The l-glycero-d-manno-heptopyranose (Hep) units for the branched core oligosaccharide Galβ(1-4)Glcβ(1-4)Hep and Hepα(1-3)Hep were prepared from the corresponding Hep building blocks. To obtain 4,5-branched core oligosaccharide structures, the common acceptor Kdoα(2-4)Kdo was glycosylated with the Hep units.

Funder

JSPS KAKENHI

Publisher

Oxford University Press (OUP)

Subject

Organic Chemistry,Molecular Biology,Applied Microbiology and Biotechnology,General Medicine,Biochemistry,Analytical Chemistry,Biotechnology

Link

http://academic.oup.com/bbb/article-pdf/79/12/1931/36821144/bbb1931.pdf

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