Synthesis of 2,2-difluoro-3H-benzothiophen-3-ol via a difluorocarbene insertion reaction, investigating the scope for further derivatization-Reference-Cited by-同舟云学术

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Synthesis of 2,2-difluoro-3H-benzothiophen-3-ol via a difluorocarbene insertion reaction, investigating the scope for further derivatization

Published:2019-05-16 Issue:16 Volume:49 Page:1997-2004
ISSN:0039-7911
Container-title:Synthetic Communications
language:en
Short-container-title:Synthetic Communications

Author:

Rodrigues Clarence¹,Hall Roger G.²,Montgomery Mark³,Yang Xiuhua⁴,Xiang Yong⁴,Lu Long⁴,Pal Sitaram¹,Manjunath Bhanu N.¹

Affiliation:

1. Syngenta Biosciences Pvt. Ltd., Santa Monica Works, Panaji, Goa, India;

2. Syngenta Crop Protection, Stein, Switzerland;

3. Syngenta Jealott’s Hill International Research Centre, Bracknell, Berkshire, UK;

4. Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, China

Publisher

Informa UK Limited

Subject

Organic Chemistry

Link

https://www.tandfonline.com/doi/pdf/10.1080/00397911.2019.1614629

Reference14 articles.

1. The Importance of Fluorine in the Life Science Industry

2. The Importance of Fluorine in the Life Science Industry

3. Fluorine in Pharmaceutical Industry: Fluorine-Containing Drugs Introduced to the Market in the Last Decade (2001–2011)

4. (a) Bruick, R. K.; Chen, Y.; Ruiz, J. C. F. HIF-2α inhibitors for treating iron overload disorders. WO2016057242.

5. (b) Josey, J. A. Preparation of indanol and cyclopentapyridinol derivatives for treating glioblastoma. WO2016145045.

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1. Recent advances in the application of ylide-like species in [4 + 1]-annulation reactions: an updated review;Organic Chemistry Frontiers;2022

2. Difluorocarbene-Mediated Cascade Cyclization: The Multifunctional Role of Ruppert–Prakash Reagent;Organic Letters;2021-04-29

3. Difluorocarbene-Triggered Cyclization: Synthesis of (Hetero)arene-Fused 2,2-Difluoro-2,3-dihydrothiophenes;Organic Letters;2020-08-20

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