Deuteration of Non-Stabilized Phosphorus Ylides With DMSO-d6: Convenient Synthesis of Mono-Deuterated Alkenes

Author:

Reitz Allen B.,Maryanoff Bruce E.

Publisher

Informa UK Limited

Subject

Organic Chemistry

Reference27 articles.

1. 1983. This work was presented at the 17th Annual Middle Atlantic Regional Meeting of the American Chemical Society, Abstract No. 337a. April6–81983, White Haven, PA. A related paper was also presented (Abstract No. 348, Perlmutter H. D. Beeman D.) pertaining to formation and use of deuterated ylides prepared by base-catalyzed exchange of the protio ylides with D2O or DOEt. See adjoining paper

2. Zur Reaktionsweise des Pentaphenyl-phosphors und einiger Derivate

3. Gosney, I. and Rowley, A. G. 1979.“Organophosphorus Reagents in Organic Synthesis,”, Edited by: Cadogan, J. I. G. 17–154. New York, NY: Academic Press. For a recent review, see

4. Additions to bicyclic olefins. VII. Electrophilic additions of hydrogen chloride and deuterium chloride to norbornene, 2-methylenenorbornane, and related bicyclic olefins. Evidence for a carbonium ion process and the capture of unsymmetrical (classical) 2-norbornyl cations

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