Convenient Synthetic Routes to 1,4-Difluoroanthracene-9,10-Dione

Author:

Krapcho A. Paul,Getahun Zelleka

Publisher

Informa UK Limited

Subject

Organic Chemistry

Reference9 articles.

1. 2 The Design, Synthesis and Development of a New Class of Potent Antineoplastic Anthraquinones

2. Zielske, A. G. 1984. 188 National Meeting of the American Chemical Society. August26–311984, Philadelphia, PA. Abstr. MEDI 56 and Showalter, H. D. H., Berman, E. M., Johnson, J. L., Atwood, J. L. and Hunter, W. E. Tetrahedron Letters 1985, 26, 157, Abstracts of Paper, For example, reaction of2a with a large excess of 1,2-diaminoethane (pyridine, room temperature, 8 h) leads to1c (80–90%). b. During the course of our research, two reports appeared on displacement reactions for ditosylate2b (and ditriflate2c) for the preparation of substituted anthracene-9,10-diones. The difluoride2a undergoes displacements much more readily than either of these substrates. See

3. Available from Fluka (Catalog 14, 1984–1985) at $142.50 for 5 g, a rather expensive starting material

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