Fac-mer Isomerization of Mo(CO)3(Phosphite)3 Caused by Interaction Between Phosphite Oxygen and Silane Silicon
Author:
Affiliation:
1. a Kobe City College of Technology , Kobe , Japan
2. b Department of Chemistry, Graduate School of Science , Osaka City University , Osaka , Japan
Publisher
Informa UK Limited
Subject
Inorganic Chemistry,Organic Chemistry,Biochemistry
Link
https://www.tandfonline.com/doi/pdf/10.1080/10426507.2010.520290
Reference9 articles.
1. Unusual isomeric lability in both oxidation states of the redox systems fac-/mer[M(CO)3(.eta.3-P2P')]+/M(CO)3(.eta.3-P2P') (M = Cr,Mo,W; P2P' = bis(2-(diphenylphosphino)ethyl)phenylphosphine): the first examples where the 17-electron fac+ and mer+ isomers are of comparable stability
2. Formation and fac-mer isomerization of cationic phosphenium transition metal complexes formulated as [M(bpy)(CO)3{Me}]+ (M Cr, Mo, W) and [M(dppe)(CO)3{Me}]+ (M Mo, W)
3. The mechanism of facial-meridional isomerism in octahedral metal carbonyl complexes: fac-[1,2-bis(diphenylphosphino)ethane](triisopropyl phosphite)tricarbonylmolybdenum(0)
4. Kinetics and mechanism of ligand substitution in [Cr(π-ligand)(CO)3] complexes (ligand = naphthalene, pyrene, thiophene, 2,6-dimethylpyridine, or cycloheptatriene) and of fac/mer isomerization in [M(CO)3L3](M = Cr, Mo or W; L = phosphite, phosphine or isocyanide)
5. Larson , G. L. 1989. The Chemistry of Organic Silicon Compounds, Edited by: Patai , S. and Rappoport , Z. 76–78. London: Wiley.
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