Ab initiodetermination of the heat of formation of ketenyl (HCCO) and ethynyl (CCH) radicals
Author:
Publisher
Informa UK Limited
Subject
Physical and Theoretical Chemistry,Condensed Matter Physics,Molecular Biology,Biophysics
Link
http://www.tandfonline.com/doi/pdf/10.1080/00268970500131124
Reference93 articles.
1. Rate constants for the reactions O + C2H2 and O + C2D2 .fwdarw. products, over the temperature range .apprx.850-1950 K, by the flash photolysis-shock tube technique. Determination of the branching ratio and a further theoretical analysis
2. Product distributions of the acetylene + atomic oxygen and HCCO (ketenyl) + atomic hydrogen reactions. Rate constant of methylene(.apprx.X3B1) + atomic hydrogen
3. Branching ratio of the C2H2 + O reaction at 290 K from kinetic modelling of relative methylene concentration versus time profiles in C2H2/O/H systems
4. The mechanism of the homogeneous pyrolysis of acetylene
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