The Reaction of Unsaturated Carbonyl Compounds with “Activated” Sulfur. Part 3.1 Reaction Course-Reference-Cited by-同舟云学术

The Reaction of Unsaturated Carbonyl Compounds with “Activated” Sulfur. Part 3.1 Reaction Course

Published:1998-02-01 Issue:1 Volume:134 Page:463-474
ISSN:1042-6507
Container-title:Phosphorus, Sulfur, and Silicon and the Related Elements
language:en
Short-container-title:Phosphorus, Sulfur, and Silicon and the Related Elements

Author:

Chiacchio Ugo¹²³⁴⁵,Corsaro Antonino¹²³⁴⁵,Pistarà Venerando¹²³⁴⁵,Rescifina Antonio¹²³⁴⁵,Purrello Giovanni¹²³⁴⁵

Affiliation:

1. a Dipartimento di Scienze Chimiche , Università di Catania , Viale A. Doria 6, 95125 Catania, (Italy)

2. b Dipartimento di Scienze Chimiche , Università di Catania , Viale A. Doria 6, 95125 Catania, (Italy)

3. c Dipartimento di Scienze Chimiche , Università di Catania , Viale A. Doria 6, 95125 Catania, (Italy)

4. d Dipartimento di Scienze Chimiche , Università di Catania , Viale A. Doria 6, 95125 Catania, (Italy)

5. e Dipartimento di Scienze Chimiche , Università di Catania , Viale A. Doria 6, 95125 Catania, (Italy)

Publisher

Informa UK Limited

Subject

Inorganic Chemistry,Organic Chemistry,Biochemistry

Link

https://www.tandfonline.com/doi/pdf/10.1080/10426509808545487

Reference19 articles.

1. The Reaction of Unsaturated Carbonyl Compounds with "Activated" Sulfur (II). Formation of Cyclic Disulfide and Polysulfides

2. The Reaction of Unsaturated Carbonyl Compounds with "Activated" Sulfur

3. Data relative to reactions of unsaturated ketones 1a, b, and 10-12, sulfur and tertiary amines are under elaboration and will be reported in due course.

4. It is well known that the sulfur in the presence of phosphines,5 amines6 and ammonia7 acts as a “nucleo-electrophilic thiation reagent”8 since these nucleophiles open the sulfur eight membered ring affording nucleophilic and electrophilic species, also at room temperature.

5. Reactions of Elemental Sulfur. I. The Uncatalyzed Reaction of Sulfur with Triarylphosphines1