Solution Equilibria and Kinetic Studies of the Copper(II) Promoted Hydrolysis of 8-Quinolyl Phosphate. A Large Rate Enhancement for the Hydrolysis of a Phosphate Monoester Dianion-Reference-Cited by-同舟云学术

Solution Equilibria and Kinetic Studies of the Copper(II) Promoted Hydrolysis of 8-Quinolyl Phosphate. A Large Rate Enhancement for the Hydrolysis of a Phosphate Monoester Dianion

Published:1991-06 Issue:1-4 Volume:23 Page:43-55
ISSN:0095-8972
Container-title:Journal of Coordination Chemistry
language:en
Short-container-title:Journal of Coordination Chemistry

Author:

Hay Robert W.¹,Basak Arup K.¹,Pujari Mahesh P.¹,Perotti Angelo²

Affiliation:

1. a Chemistry Department , University of Stirling , Stirling , FK9 4LA , UK

2. b Dipartimento di Chimica Generate , Viale Taramelli 12, 27100 , Pavia , Italy

Publisher

Informa UK Limited

Subject

Materials Chemistry,Physical and Theoretical Chemistry

Link

https://www.tandfonline.com/doi/pdf/10.1080/00958979109408241

Reference22 articles.

1. Cooperman , B. S. 1976. “Metal Ions in Biological Systems”, Edited by: Sigel , H. Vol. 5, 80New York: Marcel Dekker. el seq.

2. Mechanism of cobalt(III)-promoted hydrolysis of triphosphate ion

3. Hydrolysis of phosphate esters bound to cobalt(III). Kinetics and mechanism of intramolecular attack of hydroxide on coordinated 4-nitrophenyl phosphate

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1. Comparison of Cu(II)-Promoted Leaving Group Stabilization of the Cleavage of a Homologous Set of Phosphate Mono-, Di-, and Triesters in Water, Methanol, and Ethanol;Inorganic Chemistry;2012-03-07

2. Biomimetic and Nonbiological Dinuclear Mx+Complex-Catalyzed Alcoholysis Reactions of Phosphoryl Transfer Reactions;Progress in Inorganic Chemistry;2011-12-19

3. Demonstration of Prominent Cu(II)-Promoted Leaving Group Stabilization of the Cleavage of a Homologous Set of Phosphate Mono-, Di-, and Triesters in Methanol;Journal of the American Chemical Society;2010-02-17

4. Hydrolysis of 8-Quinolyl Phosphate Monoester: Kinetic and Theoretical Studies of the Effect of Lanthanide Ions;The Journal of Organic Chemistry;2008-12-24

5. Dissociative Solvolytic Cleavage of Methyl (ortho-Carboxymethyl)Aryl Phosphate Diesters Mediated by Yb3+ in Methanol Gives a 1012-Fold Rate Acceleration Attributable to Leaving Group Assistance;Journal of the American Chemical Society;2008-12-04