MECHANISM OF DISPLACEMENT OF ALKANES FROM PHOTOGENERATED (ALKANE) Cr(CO)5 COMPLEXES
Author:
Affiliation:
1. a Department of Chemistry , University of North Texas , Denton, TX, 76203, USA
2. b Proctor and Gamble Co., Miami Valley Laboratory , P.O. Box 39707, Cincinnati, OH, 45239, USA
Publisher
Informa UK Limited
Subject
Materials Chemistry,Physical and Theoretical Chemistry
Link
https://www.tandfonline.com/doi/pdf/10.1080/00958979908022225
Reference8 articles.
1. Femtosecond Infrared Studies of the Dissociation and Dynamics of Transition Metal Carbonyls in Solution
2. Pentacarbonylchromium-solvent complexes
3. Mechanism of Linkage Isomerization in (η1-5-Chloropentene)pentacarbonylchromium(0)
4. TheseLwhave several binding modes to Cr available to them: “agostic,” through a -C-H-Cr two-electron, three-center interaction,viaeither an arene ring-center or edge, or through a lone pair on a substituted halogen, Cl or Br; see Refs. [2,3].
5. Carbonhydrogen-transition metal bonds
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2. Solvent/C60 exchange on Ir(CO)(PPH3)2(Cl)(η2-C60) and solvent/solvent’ exchange on Ir(CO)(PPH3)2(Cl)(solvent);Inorganic Chemistry Communications;2009-05
3. Reactions of the transient species Cr(CO)5(cyclohexane) with C4HnE (n = 4, 8; E = O, NH, S) studied by time-resolved IR absorption spectroscopy;Dalton Trans.;2007
4. Displacement of the heptane solvent from (η5-C5H5)Re(CO)2(heptane): A flash photolysis study using infrared detection;Journal of Organometallic Chemistry;2005-11
5. On the use of ?fast kinetics? to determine the mechanism of ligand substitution at a solvated transition-metal intermediate;International Journal of Chemical Kinetics;2004
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