Crystal Structures for the Electron Donor Dibenzotetrathiafulavalene, DBTTF, and Its Mixed-stack Charge-transfer Salts with the Electron Acceptors 7,7,8,8-tetracyano-p-quinodimethane, TCNQ, and 2,5-difluoro-7,7,8,8-tetracyano-p-quinodimethane, 2,5-TCNQF2

Author:

Emge Thomas J.1,Wiygul F. Mitchell1,Chappell John S.1,Bloch Aaron N.2,Ferraris John P.3,Cowan Dwaine O.1,Kistenmacher Thomas J.1

Affiliation:

1. a Contribution from the Department of Chemistry , The Johns Hopkins University , Baltimore , Maryland , 21218

2. b Department of Chemistry , The University of Texas at Dallas , P. O. Box 668, Richardson , Texas , 75080

3. c Corporate Research Laboratory , Exxon Research and Engineering Company , Linden , New Jersey , 07036

Publisher

Informa UK Limited

Reference69 articles.

1. Electrical conductivity by the bis(1,3-dithiole)-bis(1,3-dithiolium) system

2. Substituted Quinodimethans. II. Anion-radical Derivatives and Complexes of 7,7,8,8-Tetracyanoquinodimethan

3. Abbreviations employed are as follows;donors: TTF = tetrathiafulvalene, HMTTF = hexamethylenetetrathiafulvalene, DBTTF = dibenzotetrathiafulvalene, TSF = tetraselenafulvalene, TMTSF = tetramethyltetraselenafulvalene, HMTSF = hexamethylenetetraselenafulvalene;acceptors: TCNQ = tetracyanoquinodimethane; 2.5-TCNQC12 = 2,5-dichloro-tetracyanoquinodimethane, 2,5-TCNQF2 = 2,5-difluoro- tetracyanoquinodimethane, TCNQF4 = tetrafluoro-tetracyanoquinodimethane

4. The crystal structure of the 1:1 radical cation–radical anion salt of 2,2'-bis-l,3-dithiole (TTF) and 7,7,8,8-tetracyanoquinodimethane (TCNQ)

5. Electron transfer in a new highly conducting donor-acceptor complex

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