Zinc sulfide chemical vapor deposition optical ceramic analyzed by XPS

Author:

Butkus Brian1ORCID,Kostogiannes Alexandros12ORCID,Howe Andrew2ORCID,Kang Myungkoo2ORCID,Gaume Romain23ORCID,Richardson Kathleen A.12ORCID,Banerjee Parag1345ORCID

Affiliation:

1. Department of Materials Science and Engineering, University of Central Florida 1 , Orlando, Florida 32816

2. College of Optics & Photonics, University of Central Florida 2 , Orlando, Florida 32816

3. NanoScience Technology Center, University of Central Florida 3 , Orlando, Florida 32816

4. Florida Solar Energy Center, University of Central Florida 4 , Orlando, Florida 32816

5. REACT Faculty Cluster, University of Central Florida 5 , Orlando, Florida 32816

Abstract

Commercially available zinc sulfide (ZnS) ceramics, synthesized using chemical vapor deposition and subsequently hot isostatically pressed, are optically transparent as compared to other zinc sulfide chemical vapor deposited films and ceramics. The unique optical transparency along with the hardness and chemical resistance of ZnS makes it an important material for infrared transmission applications. X-ray photoelectron spectroscopy and x-ray induced Auger electron spectroscopy were performed on an optically transparent ZnS ceramic. This report includes charge corrected scans for the survey along with S 2s, S 2p, S LMM, Zn 2p, Zn 2s, Zn 3d, Zn 3p, Zn 3s, Zn LMM, O 1s, and C 1s surface photoelectron signals. The scans provide photoelectron spectroscopy investigation data to help with the identification of metal sulfide compounds.

Funder

Division of Electrical, Communications and Cyber Systems

Florida High Tech Corridor Council

Publisher

American Vacuum Society

Subject

Surfaces, Coatings and Films,Surfaces and Interfaces,Condensed Matter Physics

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