Shakhdaraite-(Y), ScYNb2O8, from the Leskhozovskaya granitic pegmatite, the valley of the Shakhdara River, southwestern Pamir, Gorno-Badakhshanskii Autonomous Region, Tajikistan: New mineral description and crystal structure

Author:

Pautov Leonid A.12,Mirakov Mirak A.3,Sokolova Elena4,Day Maxwell C.4,Hawthorne Frank C.4,Schodibekov Manuchekhr A.3,Karpenko Vladimir Yu.1,Makhmadsharif Saimudasir3,Faiziev Abdulkhak R.3

Affiliation:

1. A.E. Fersman Mineralogical Museum, Russian Academy of Sciences, Leninskiy Prospekt 18-2, Moscow 119071, Russia

2. Federal State Budgetary Institute of Science, South Urals Research Center of Mineralogy and Geoecology, Urals Branch, Russian Academy of Sciences; SU FRC MG UB RAS, Miass, Chelyabinsk District, 456317, Russia

3. Institute of Geology, Earthquake Engineering and Seismology, National Academy of Sciences of Tajikistan, Aini avenue, 267, Dushanbe, 734063, Tajikistan

4. Department of Earth Sciences, University of Manitoba, 125 Dysart Road, Winnipeg, Manitoba R3T 2N2, Canada

Abstract

ABSTRACT Shakhdaraite-(Y), ideally ScYNb2O8, is a new mineral from the Leskhozovskaya miarolitic granitic pegmatite at the Shakhdara River, southwestern Pamir (Tajikistan). Shakhdaraite-(Y) occurs mainly as grains from 10 to 150 μm in size in a near-miarolitic pegmatite complex in association with quartz, albite, pyrochlore-microlite, fersmite, and an unnamed Sc-Nb oxide; only one large, single, well-shaped crystal 200 μm long was found in a small cavity with quartz, albite, bertrandite, pyrochlore, and jarosite. Shakhdaraite-(Y) is black to dark-brown, streak is brown. Luster is vitreous semi-metallic. It is brittle with conchoidal fracture. Mohs hardness is 5. VHN100 = 436 kg/mm2. Dcalc. = 5.602 g/cm3. In reflected light, it is light gray and its reflective capacity is moderate to low. Anisotropy is distinct, without color effects. Pleochroism was not observed. Internal reflections are red-brown. Reflectance values were measured in air with SiC as reference material [λ(nm), Rmax, Rmin]: 470, 14.6, 13.9; 546, 14.0, 13.4; 589, 13.9, 13.3; 650, 13.8, 13.1. Electron probe microanalysis (WDS mode, 7 points) gives (wt.%): Nb2O5 50.70; Ta2O5 4.52; TiO2 0.08; WO3 0.79; SnO2 1.54; CaO 1.01; Sc2O3 11.35; MnO 1.38; FeO 0.01; Y2O3 12.00; Ce2O3 0.21; Pr2O3 0.04; Nd2O3 0.27; Sm2O3 0.32; Eu2O3 0.07; Gd2O3 0.86; Tb2O3 0.22; Dy2O3 2.07; Ho2O3 0.29; Er2O3 1.33; Tm2O3 0.35; Yb2O3 2.80; Lu2O3 0.32; PbO 0.24; ThO2 1.90; UO2 3.30, total 97.97. The empirical formula of shakhdaraite-(Y) based on O = 8 apfu (atoms per formula unit) is (Nb1.91Sc0.83Y0.53Ta0.10Mn0.10Ca0.09 Yb0.07U4+0.06Dy0.06Sn0.05Th0.04Er0.03Gd0.02W6+0.02Pb0.01Ce0.01Nd0.01Sm0.01Tb0.01Ho0.01Tm0.01Lu0.01Ti0.01)Σ4.00O8, Z = 2. The simplified formula is Sc(Y,Yb)Nb2O8, where Yb is the dominant lanthanoid. Shakhdaraite-(Y) is monoclinic, space group P2/c, a 9.930(2), b 5.6625(11), c 5.2108(10) Å, β 92.38(3)°, V 292.7(5) Å3, Z = 2. The crystal structure was solved by direct methods [R1 = 0.0269, 878 unique reflections (F > 4σF)]. There are three cation M sites: [6]M(1) = Nb2apfu, [6]M(2) = Sc apfu, and [8]M(3) = Y apfu, ideally M = ScYNb2apfu. The M(1) and M(2) octahedra each form a brookite chain along c. The Y-dominant [8]M(3A) polyhedra form a brookite-like kinked chain, and each M(3A) polyhedron of one brookite-like chain shares two edges with the two M(3A) polyhedra from the adjacent brookite-like chain, thus forming a [Y2O8]10– layer. In the structure of shakhdaraite-(Y), M(1A) and M(2) brookite chains and a layer of [8]-coordinated M(3A) polyhedra alternate along a. Shakhdaraite-(Y) is isostructural with samarskite-(Y), ideally YFe3+Nb2O8. Shakhdaraite-(Y) [Russian Cyrillic: шахдараит-(Y)] is named after its type locality: the valley of the Shakhdara River in the southwest of the Pamir Mountains.

Publisher

Mineralogical Association of Canada

Subject

Geochemistry and Petrology

Reference35 articles.

1. Astrelina, E., Smirnov, S., Ragozin, A., Karmanov, N., & Konovalenko,S. (2011) Late magmatic crystallization in the tourmaline-bearing miarolitic granitic pegmatites (by example of Shakhdarinskaya and Leskhozovskaya veins, SW Pamir, Tajikistan). ECROFI-XXI, Leoben, Austria, Abstracts, 24–25.

2. Britvin, S.N., Pekov, I.V., Krzhizhanovskaya, M.G., Agakhanov, A.A., Ternes, B., Schüller, W., & Chukanov,N.V. (2019) Redefinition and crystal chemistry of samarskite-(Y), YFe3+Nb2O8: Cation-ordered niobate structurally related to layered double tungstates. Physics and Chemistry of Minerals46, 727– 741.

3. Budanov, V.I. (1993) Endogenic Formations of Pamir . Donish, Dushanbe, Tajikistan(in Russian).

4. Budanova, K.T. & Budanov,V.I. (1983) Metamorphic Formations of South-Western Pamir . Donish, Dushanbe, Russia(in Russian).

5. Černý, P. & Chapman,R. (2001) Exsolution and breakdown of scandian and tungstenian Nb–Ta–Ti–Fe–Mn phases in niobian rutile. Canadian Mineralogist39, 93– 101.

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