Controlling Single Molecule Conjugated Oligomers and Polymers with DNA

Abstract

AbstractThe unique specificity of DNA interactions and our ability to synthesize artificial functionalized DNA sequences makes it the ideal material for controlling self-assembly and chemical reactions of components attached to DNA sequences. Inspired by the field of molecular electronics and the lack of methods to assemble molecular components, we have explored the organization of conjugated molecular components using DNA-based self-assembly. In this chapter, we provide an overview of our efforts first to assemble and chemically couple conjugated molecules directed by DNA, and more recently to assemble conjugated polymers in DNA nanostructures. At the end of the chapter, we provide a short overview of work by other groups in the field.