What process causes the slowdown of pressure solution creep

Author:

Lu RenchaoORCID,Cheng ChaojieORCID,Nagel ThomasORCID,Milsch HaraldORCID,Yasuhara HideakiORCID,Kolditz OlafORCID,Shao HaibingORCID

Abstract

Abstract The slowdown of pressure solution creep has been thought to be caused by stress redistribution. This study presents a fresh view towards this creep behaviour. Basically, two rate-limiting mechanisms come into play amid pressure solution creep: (1) stress redistribution across expanding inter-granular contacts and (2) solute accumulation in the water film. Because non-hydrostatic dissolution occurs under open system conditions, solute accumulation in the water film is constrained by the ensuing solute transport process. Relying on the matter exchange across the contact surface boundary, the active processes in the voids, e.g., solute migration and deposition, affect pressure solution creep. Based upon the above, we sum up two requirements that have to be met for achieving chemical compaction equilibrium: (1) the Gibbs free energy of reaction, i.e., the driving force of non-hydrostatic dissolution process, gets depleted and (2) the concentration gradient between the water film and surrounding pore water vanishes. Highlights The slowdown of pressure solution creep is a combined result of stress migration across contacts and solute accumulation in the water film. Matter exchange with the surroundings inhibits solute accumulation in the water film. This article identifies two prerequisites that need to be fulfilled for achieving chemical compaction equilibrium.

Funder

Bundesministerium für Bildung und Forschung

Helmholtz-Zentrum für Umweltforschung GmbH - UFZ

Publisher

Springer Science and Business Media LLC

Subject

Economic Geology,General Energy,Geophysics,Geotechnical Engineering and Engineering Geology

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