Assessment and source identification of heavy metal contamination of groundwater using geospatial technology in Gadilam River basin, Tamil Nadu, India

Abstract

AbstractThe purpose of this study is to determine the groundwater quality of the Gadilam River basin on the basis of Geographic Information Technology (GIS) taxonomy evaluation and risk assessment and statistical analysis. The Gadilam River originates from the district of Kallakurichi and flows into the district of Viluppuram finally confluence at Bay of Bengal in the district of Cuddalore. Groundwater supplies are serving the entire drinking needs of the residents of the Gadilam River basin, and pollution of its toxic elements has been raised in recent years. A total of 120 groundwater samples, excluding reserved forest areas, were obtained from the Gadilam River basin. 50 samples of the Archaean formation, 34 samples of the Quaternary formation, 35 additional Tertiary formation samples and one Cretaceous formation sample. During the monsoon season (Nov. 2018), groundwater samples were taken, which is after the Gaja cyclone’s diastral effects. At the time of the sample acquisition, pH, EC and TDS were measured using the Elico field kit. Using the Atomic Absorption Spectrometer, the heavy metals Zn, Cr, Cu, Pb, Co, Fe, Mn and Ni were analyzed. The spatial distribution maps of the GIS shows that in all the samples the concentrations of chromium, lead, cobalt, nickel are high (above the permitted limit). In 93.40%of the area, the manganese concentrations are higher, dropping under the unauthorized cap for human use in compliance with WHO requirements. In addition, statistical analysis indicates that groundwater pollution of the roots of Pb and Cr is from foreign sources and geogenic origin cannot be avoided. The country's rocks and industrial effluents can trigger Zn and Co. The anthropogenic operations may be due to Cu. The taxonomy diagram showing all groundwater samples is classified as ‘near neutral high metal.’ Industrial waste, household sewage, has boosted the emission of heavy metals. Groundwater risk assessment study of heavy metals using SMCE approach reveals that dense residential area in the Archaean formation, lineaments intersection with river portion and sea shore area in Quaternary formation and nearby SIPCOT industry and Lignite mining area in Tertiary formation is noted in the ‘Extreme risk dangerous’ areas.