Acids, Bases, and the Nature of the Hydrogen Ion

Author:

Bell R. P.

Publisher

Springer US

Reference101 articles.

1. J. N. Brönsted, Rec. Tray. Chim., 42, 718 (1923).

2. It is frequently stated that the acid-base definition given here was put forward almost simultaneously by Brönsted and by T. M. Lowry [Chem. and Ind.,42, 43 (1923)]. However, although Lowry's paper undoubtedly contains many of the ideas underlying this definition, especially for bases, it does not contain an explicit definition, and it is nowhere made clear that Lowry at that time regarded NH4 as an acid or CH3CO

3. as a base. In fact, in a later paper [J. Chem. Soc.,2562 (1927)], Lowry himself writes, More novelty is to be found in the perfectly logical conclusion of Brönsted that the anion of an acid is also a base or proton acceptor, in view of the fact that it can combine with a proton to form a molecule of the undissociated acid': hence it does not seem justifiable to regard Lowry as one of the originators of the definition. I am indebted to the late Professor E. A. Guggenheim for calling my attention to this point. It is also noteworthy that G. N. Lewis (Valency and the Structure of Atoms and Molecules,(Reinhold, New York, 1923, p. 141) gave the same acid-base definition, and wrote, '… we may regard the ammonium ion as an acid'. However, he did not follow up the consequences of this view, and preferred the alternative definition of acids with which his name is usually associated.

4. P. Walden, Salts, Acids, and Bases: Electrolytes: Stereochemistry, Cornell, New York, 1929.

5. J. L. Gay-Lussac, Gab., Ann. Phys., 48, 341 (1814).

Cited by 2 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Acids and Acid Catalysis-Homogeneous;Encyclopedia of Catalysis;2011-05-13

2. Acids and Acid Catalysis - Homogeneous;Encyclopedia of Catalysis;2002-07-15

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3