High performing platinum—copper catalyst for self—breathing polymer electrolyte membrane fuel cell

Abstract

AbstractPlatinum (Pt) is the most common catalyst in Polymer Electrolyte Membrane Fuel Cells due to its ability to effectively promote the oxidation of hydrogen and reduction of oxygen. However, as a noble metal, the use of Pt should be minimized. Alloying Pt with low-cost transition metals is an effective strategy to improve catalytic activity and reduce Pt use. In this context, we report on a one-step synthesis of a Platinum/Copper (PtCu) catalyst, which can be used at both the anode and the cathode of a fuel cell. Catalysts with various Cu to Pt ratios were synthesised and in particular the PtCu catalyst at a Cu to Pt ratio of 0.5 demonstrated a high activity for hydrogen oxidation and oxygen reduction, i.e. 2.4 times superior to Pt alone. This enhanced catalytic activity was confirmed in a self-breathing PEMFC with a power output of 45.16 mW cm−2, which corresponds to a 1.4-fold increase compared to Pt alone. This is a significant improvement because 40% more power was obtained with 22% less Pt. Graphical Abstract