Author:
Omann Kristian Juul,Sharma Raghunandan,Andersen Shuang Ma
Abstract
AbstractThis study revisits the impacts of the presence of OH− and Cl− anions and/or different forms of Pt precursors during polyol synthesis of carbon-supported electrocatalysts. Efficiency of the synthesis process in terms of the %conversion of a Pt complex to Pt metal has been quantified. It is observed that Pt precursors based on [PtCl6]2− are reduced easily compared to those based on [Pt(OH)6]2−. Furthermore, presence of excess Cl− during synthesis results in decreased %conversion and reduced ECSA, which is opposite from other reported work synthesized at higher temperature and pure solvents. For Pt/C synthesis under mild conditions, 100 °C and 30 vol% EG in water as solvent, presence of OH− during synthesis decreases the ECSA and hence increases the Pt nanoparticle size and change of catalyst surface structure. Finally, a method to get insights into the surface structure of Pt-nanoparticles through analysis of the H-adsorption/H-desorption peaks has been proposed.
Graphical Abstract
Funder
Innovationsfonden
Danish Agency for Science and Higher Education
EnergiFyn
University Library of Southern Denmark
Publisher
Springer Science and Business Media LLC