Synthesis and characterization of six-membered pincer nickelacycles and application in alkylation of benzothiazole

Author:

Pandiri Hanumanprasad,Sharma Dipesh M,Gonnade Rajesh G,Punji BenudharORCID

Publisher

Springer Science and Business Media LLC

Subject

General Chemistry

Reference23 articles.

1. (a) Morales-Morales D and Jensen C M 2007 In The Chemistry of Pincer Compounds (Amsterdam: Elsevier); (b) Szabó K J and Wendt O F 2014 In Pincer and Pincer-Type Complexes: Applications in Organic Synthesis and Catalysis (Weinheim: Wiley-VCH); (c) Albrecht M and van Koten G 2001 Platinum Group Organometallics Based on “Pincer” Complexes: Sensors, Switches, and Catalysts Angew. Chem. Int. Ed. 40 3750; (d) Singleton J T 2003 The uses of pincer complexes in organic synthesis Tetrahedron 59 1837; (e) van der Vlugt J I and Reek J N H 2009 Neutral Tridentate PNP Ligands and Their Hybrid Analogues: Versatile Non-Innocent Scaffolds for Homogeneous Catalysis Angew. Chem. Int. Ed. 48 8832

2. van der Boom M E and Milstein D 2003 Cyclometalated Phosphine-Based Pincer Complexes: Mechanistic Insight in Catalysis, Coordination, and Bond Activation Chem. Rev. 103 1759

3. Moulton C J and Shaw B L 1976 Transition metal-carbon bonds. Part XLII. Complexes of nickel, palladium, platinum, rhodium and iridium with the tridentate ligand 2,6-bis[(di-t- butylphosphino)methyl]phenyl J. Chem. Soc., Dalton Trans. 1020

4. (a) Grove D M, van Koten G, Zoet R, Murrall N W and Welch A J 1983 Unique stable organometallic nickel(III) complexes; syntheses and the molecular structure of $$[\text{Ni}[\text{ C }_{6}\text{ H }_{3}(\text{ CH }_{2}\text{ NMe }_{2})_{2}\text{-2 },6]\text{ I }_{2}]$$ [ Ni [ C 6 H 3 ( CH 2 NMe 2 ) 2 -2 , 6 ] I 2 ] J. Am. Chem. Soc. 105 1379; (b) Grove D M, van Koten G, Ubbels H J C, Zoet R and Spek A L 1984 Organonickel(II) complexes of the tridentate monoanionic ligand o,o’-bis[(dimethylamino)methylphenyl (N-C-N). Syntheses and the x-ray crystal structure of the stable nickel(II) formate [Ni(N-C-N) $$\text{ O }_{2}\text{ CH }$$ O 2 CH ] Organometallics 3 1003

5. (a) Cámpora J, Palma P, del Rıo D, M C M and Álvarez E 2004 Synthesis and Reactivity of a Mononuclear Parent Amido Nickel Complex. Structures of Ni[ $$\text{ C }_{6}\text{ H }_{3}\text{-2 },\text{6- } (\text{ CH }_{2}\text{ P }^{i}\text{ Pr }_{2})_{2}](\text{ NH }_{2})$$ C 6 H 3 -2 , 6- ( CH 2 P i Pr 2 ) 2 ] ( NH 2 ) and Ni[ $$\text{ C }_{6}\text{ H }_{3}\text{-2 },\text{6- }(\text{ CH }_{2}\text{ P }^{i}\text{ Pr }_{2})_{2}$$ C 6 H 3 -2 , 6- ( CH 2 P i Pr 2 ) 2 ](OMe) Organometallics 23 5653; (b) Cámpora J, Palma P, del Rıo D and Eleuterio Á 2004 CO Insertion Reactions into the M-OH Bonds of Monomeric Nickel and Palladium Hydroxides. Reversible Decarbonylation of a Hydroxycarbonyl Palladium Complex Organometallics 23 1652; (c) Boro B J, Duesler E N, Goldberg K I and Kemp R A 2009 Synthesis, Characterization, and Reactivity of Nickel Hydride Complexes Containing 2,6- $$\text{ C }_{6}\text{ H }_{3}(\text{ CH }_{2}\text{ PR }_{2})_{2}$$ C 6 H 3 ( CH 2 PR 2 ) 2 ( $$R = {}^{t}\text{ Bu }$$ R = t Bu , $${}^{c}\text{ Hex }$$ c Hex , and $${}^{i}\text{ Pr }$$ i Pr ) Pincer Ligands Inorg. Chem. 48 5081; (d) Schmeier T J, Hazari N, Incarvito C D and Raskatov J A 2011 Exploring the reactions of $$\text{ CO }_{2}$$ CO 2 with PCP supported nickel complexes Chem. Commun. 47 1824; (e) Schmeier T J, Nova A, Hazari N and Maseras F 2012 Synthesis of PCP-Supported Nickel Complexes and their Reactivity with Carbon Dioxide Chem. - Eur. J. 18 6915; (f) Connelly S J, Zimmerman A C, Kaminsky W and Heinekey D M 2012 Synthesis, Structure, and Reactivity of a Nickel Dihydrogen Complex Chem. - Eur. J. 18 15932; (g) Yang Z, Liu D, Liu Y, Sugiya M, Imamoto T and Zhang W 2015 Synthesis and Structural Characterization of Nickel Complexes Possessing P-Stereogenic Pincer Scaffolds and Their Application in Asymmetric Aza-Michael Reactions Organometallics 34 1228

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