Empirical model for the effect of air humidity during manufacturing on the glass transition temperature of carbon fiber reinforced hot curing epoxy – a case study

Abstract

AbstractCarbon fiber-epoxy laminates are used in aerospace manufacturing, e.g. as substrates for solar cells of satellites. Commonly, fibers or fibermats are impregnated with epoxy resin and placed in the required orientation. During subsequent curing, the resin molecules are crosslinked. Cured parts are characterized by their glass transition temperature (Tg). It has been observed that Tg of epoxy matrix resin vary with recorded absolute air humidity during wet fiber placement manufacturing. Based on the production data of a series production of 203 carbon fiber laminates for space application, an empirical linear relationship between the absolute air humidity at the beginning of each production day and the observed glass transition temperature of the fully cured laminate is formulated and validated. The empirical equation describes a linear decrease of achievable glass transition temperature with increasing absolute air humidity. The quantitative nature of the results encourages straightforward practical application to determine the maximum achievable Tg for given production conditions.