Determination of nuclear graphite impurities by prompt gamma activation analysis to support decommissioning operations

Author:

Mossini ErosORCID,Revay Zsolt,Camerini Andrea,Giola Marco,Magugliani Gabriele,Macerata Elena,Mariani Mario

Abstract

AbstractElemental composition of non-irradiated nuclear grade graphite was determined by Prompt Gamma Activation Analysis (PGAA) to quantitively assess some neutron activation precursors. The knowledge of these data is paramount for an accurate radiological characterization of the material before decommissioning of graphite-moderated nuclear reactors. Bulk results of most of the nuclides were consistent with benchmark Inductively Coupled Plasma–Mass Spectrometry (ICP-MS) and literature data. In the case of 14N and 35Cl, depth distribution profiles were observed and quantified for the first time. These outcomes could shine a light on 14C and 36Cl depth distribution profiles and fractional release during leaching experiments.

Funder

Politecnico di Milano

Publisher

Springer Science and Business Media LLC

Subject

Health, Toxicology and Mutagenesis,Public Health, Environmental and Occupational Health,Spectroscopy,Pollution,Radiology, Nuclear Medicine and imaging,Nuclear Energy and Engineering,Analytical Chemistry

Reference32 articles.

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2. Ojovan MI, Wickham AJ (2016) Processing of Irradiated Graphite: The Outcomes of an IAEA Coordinated Research Project. In: MRS Advances

3. Wickham A, Steinmetz HJ, O’Sullivan P, Ojovan MI (2017) Updating irradiated graphite disposal: Project ‘GRAPA’ and the international decommissioning network. J Environ Radioact. https://doi.org/10.1016/j.jenvrad.2017.01.022

4. International Atomic Energy Agency (2006) TECDOC-1521: Characterization, treatment and conditioning of radioactive graphite from decommissioning of nuclear reactors

5. International Atomic Energy Agency (2010) TECDOC-1647. Progress in Radioactive Graphite Waste Management

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