Prins condensation for the synthesis of isoprene from isobutylene and formaldehyde over sillica-supported H3SiW12O40 catalysts

Author:

Yu Xue,Zhu Wanchun,Zhai Shubo,Bao Qiang,Cheng Dongdong,Xia Yanyang,Wang Zhenlu,zhang Wenxiang

Funder

National Natural Science Foundation of China

the Natural Science Foundation of Science and Technology Department of Jilin Province

Jilin Province Science and Technology research plan (key scientific research project)

Publisher

Springer Science and Business Media LLC

Subject

Physical and Theoretical Chemistry,Catalysis

Reference28 articles.

1. Dang Z, Gu J, Yu L, Zhang C (1991) Vapor-phase synthesis of isoprene from formaldehyde and isobutylene over CuSO4–MOx/SiO2 catalysts. Reac Kinet Mech Cat 43:495–500

2. Hamamoto Y, Mitsutani A (1965) Method of producing conjugated diolefins. US Patent 3 221 075

3. Mitsntani A (1966) Process for the manufacture of isoprene and isobutene. US Patent 3 284 533

4. Krzywicki A, Wilanowicz T, Malinowski S (1979) Catalytic and physico-chemical properties of the Al2O3–H3PO4 system, I. Vapor phase condensation of isobutylene and formaldehyde—the Prins reaction. React Kinet Catal Lett 11:399–403

5. Dang Z, Ding S (1987) Investigation of the surface characteristics and catalytic activity of SbxOy/SiO2 catalysts for vapor-phase synthesis of isoprene from isobutylene and formaldehyde. J Mol Catal, in Chinese 3:146–152

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